New PDF release: Inorganic Ring Systems

By Jean-Francois Labarre (auth.)

ISBN-10: 0387113452

ISBN-13: 9780387113456

ISBN-10: 3540113452

ISBN-13: 9783540113454

Content material: up to date advancements in inorganic ring platforms / J.-F. Labarre (France) -- Phosphorus (III)-nitrogen ring compounds / R. Keat (U.K.) -- Sulfur-nitrogen anions and similar compounds / T. Chivers, R.T. Oakley (Canada) -- Homocyclic sulfur molecules / R. Steudel (FRG) -- Cyclic selenium sulfides / R. Steudel (FRG), R. Laitinen (SF) -- Polyhedral oligosilsesquioxanes and their homo derivatives / M.G. Voronkov, V.I. Lavrent'yev (USSR)

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Example text

Ii) The band at 1492-cm -1 seems to be unaltered on binding. As this Raman band of guanine in DNA is a strong indication of binding to the N(7) position of guanine (see Refs. 42, 43)), it may be concluded that there is no interaction between MYKO 63 and guanine. (iii) The major relative effects in intensity are seen for ~he 1340-cm -~ band, which decreases by 13 ~ and 22~,,,, for the 1304-cm -~ band, the corresponding decreases being 31 ~ and 30~o, for set I and set II, respectively. These two bands are characteristics of adenine; more precisely, the C(5) -- N(7) stretching mode is predominant in the 1340-cm- ~ vibration whereas the 1304tern- a band strongly involves the C(8) -- N(7) bond stretch 44, 45).

Comparison of the complete spectra of the solvent (10 mM NaC104 in water) and of the solutions (MYKO 63 or M Y K O 63-DNA in the solvent) showed that the region around 1850 cm-~ can be considered to have nearly "zero Raman intensity" at least for the lower wave numbers. Thus, for each spectrum, a horizontal base-line is drawn from this point, then the solvent spectrum is subtracted taking into account a coefficient determined from the compound concentration of the solution in order to keep the horizontal base-line unchanged for the new spectrum.

This comparison was achieved by computer-subtracting variable amounts of one spectrum from another. Previously, the various spectra were normalized to the same relative Raman intensity, with the 934 cm -~ band (C10 4 symmetric stretch) as an internal standard. The intensity of the C10~- scattering measures the combined effect of such experimental factors as counting time, optical alignment and laser power. Comparison of the complete spectra of the solvent (10 mM NaC104 in water) and of the solutions (MYKO 63 or M Y K O 63-DNA in the solvent) showed that the region around 1850 cm-~ can be considered to have nearly "zero Raman intensity" at least for the lower wave numbers.

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Inorganic Ring Systems by Jean-Francois Labarre (auth.)


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