By Bruno Pignataro (ed.)
ISBN-10: 3527319182
ISBN-13: 9783527319183
Supplying a glimpse into the long run, the younger scientists contributing the following have been thought of to be an important for tomorrow's chemistry and fabrics technological know-how. They current the state-of-the-art of their specific fields of study, with subject matters starting from new man made pathways and nanotechnology to eco-friendly chemistry.
Of significant curiosity to natural chemists, fabrics scientists and biochemists.
Read Online or Download Tomorrow's Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry PDF
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Extra info for Tomorrow's Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry
Example text
H. C. (1958) The Journal of Organic Chemistry, 23, 420–7. Odian, G. (1991) Principles of Polymerization, 3rd edn, John Wiley & Sons, Ltd, New York. 1 Introduction Lithography has enabled the miniaturization revolution in modern technology, with over 800 million transistors being packed into the latest multicore processor architectures. Despite these great advances in technology, the ability of top-down approaches to access smaller and smaller architectures is limited. Therefore, the use of chemical self-assembly from molecular building blocks holds great promise to enable fabrication on the nanoscale, or even the sub-nanoscale.
No evidence was found of complexes incorporating two or three equivalents of methylated aldehyde. 13, mixtures of products were obtained. 18 Å) [41] in complexes with the same ligand; this observation was correlated with the finding that iron(II) is the only divalent first-row transition metal having a low-spin ground state with this ligand [41]. 16, in addition to the other two congeners incorporating 2 and 3 equivalents of methylated aldehyde, respectively. They determined that although 14 remains in the low-spin 1A1 state from 30 to 450 K [43, 44], the complexes containing methylated aldehyde residues undergo spin crossover to the high-spin 5T2 state as the temperature increases.
4. We sought to build more complex structures by using this motif as a tecton [30], or fundamental building block, as described below. 4 The organization of subcomponents around a metal center. 5 Construction of double helicate 3 from subcomponents. 3 ORTEP diagram of dianionic 3. 5 [17]. 2 were thus incorporated into a single phenanthrolinebis(imine) subcomponent. The geometry of the phenanthroline molecule prevents all four nitrogen atoms of one of the ligands of 3 from coordinating to a single copper(I) ion, but two copper centers may readily be chelated together to generate the helical structure of 3.
Tomorrow's Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry by Bruno Pignataro (ed.)
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