By Jean-Marie Lehn, Fumio Toda, Roger Bishop
ISBN-10: 0470854480
ISBN-13: 9780470854488
Views in Supramolecular Chemistry relates contemporary advancements and new intriguing methods in supramolecular chemistry. The sequence covers all parts from theoretical and modelling points via natural and inorganic chemistry and biochemistry to nanochemistry, fabrics, solid-state and polymer sciences reflecting the various and sundry functions of supramolecular buildings in smooth chemistry.
The layout of man-made new host compounds has improved speedily and contributed to the improvement of latest fields of supramolecular chemistry. in addition, the applying of supramolecular structures is turning into extra very important and has implications on, for instance, drugs and agriculture.
concentrating on the facets of separation and response which are particular to supramolecular chemistry, this paintings may be of price to investigate chemists, engineers and graduate scholars, not just within the box of supramolecular chemistry, yet within the wider zone of pharmaceutical chemistry, eco-friendly chemistry and agriculture.
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Extra info for Separations and reactions in organic supramolecular chemistry
Example text
Two independent 54 Separations in Supramolecular Chemistry Figure 21 Part of the crystal structure of (14)2 ·(DMSO) projected in the ab plane, showing the O–H · · · O=S and C–F · · · H–CH2 –SO interactions (dashed lines) present between the two components. Atom designators: O heavy stippling, S black, and F vertical hatching. host molecules (A and B) are involved. In (+)-crystals only A and B* molecules are present, while in (−)-crystals only A* and B crystals are present (where * indicates molecules of the opposite handedness).
1 A ˚ diameter) (c. 8 A) contain large bulges and therefore are able to accommodate much larger guests. Thiourea tubulate crystals normally form in space group R3c and therefore are achiral. Thus, unlike urea, the thiourea tubes cannot be used for chiral separations, chiral polymerisation reactions [16,17], and related experiments. 3 Hosts Exhibiting Atropisomerism Gossypol is a natural product isolated from the cotton plant, and has the binaphthyl structure 3. Its molecular structure is formally achiral in the sense that it can be drawn with a plane and a centre of symmetry.
H. Lee, Chem. , 1986, 109. 15. D. Seebach, A. K. Beck and A. Heckel, Angew. , Int. Ed. 2001, 40, 92, and references cited therein. 16. F. Toda, in Advances in Supramol. , 1992, 2, 149. 17. F. Toda, in Advances in Supramol. , ed. G. W. Gokel, 1995, JAI Press, London, 2, 141. 18. F. Toda, K. Tanaka and A. Seikawa, J. Chem. , Chem. , 1987, 279. 19. G. Kaupp, J. Schmeyers, F. Toda and H. Koshima, J. Phys. Org. , 1996, 29, 137. 20. F. Toda and Y. Tohi, J. Chem. , Chem. , 1993, 1238. 21. K. Tanaka and F.
Separations and reactions in organic supramolecular chemistry by Jean-Marie Lehn, Fumio Toda, Roger Bishop
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