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By E Phillip Muntz; John F Wendt

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1) where p is the pressure on the system and V the volume of the gas. 2) so that the work done on the system is also given by w = I Vdp . 4) A so that the work required for a reversible, isothermal separation is equal to the Gibbs free energy change of the system. ,brings about a more ordered, less random, arrangement). 4) yields . 5 where pf and pi represent the final and initial pressures, respectively. 5) is frequently illustrated with the use of the concept of ideal semi-permeable membranes.

Figure 1 1 1 . 2 i s a schematic r e p r e s e n t a t i o n of a simple s e p a r a t i o n cascade. I n a s i m p l e c a s c a d e , a f e e d stream i s d i v i d e d i n t o a s t r e a m e n r i c h e d i n t h e s p e c i f i e d component and a stream d e p l e t e d i n t h e s p e c i f i e d component, termed p r o d u c t and waste, r e s p e c t i v e l y ; however, i n a more g e n e r a l c a s e t h e r e may be b o t h s i d e w i t h d r a w a l streams and a d d i t i o n a l f e e d streams.

I n a s i m p l e c a s c a d e , a f e e d stream i s d i v i d e d i n t o a s t r e a m e n r i c h e d i n t h e s p e c i f i e d component and a stream d e p l e t e d i n t h e s p e c i f i e d component, termed p r o d u c t and waste, r e s p e c t i v e l y ; however, i n a more g e n e r a l c a s e t h e r e may be b o t h s i d e w i t h d r a w a l streams and a d d i t i o n a l f e e d streams. 1) F = P + W , and t h e s p e c i f i e d component m a t e r i a l b a l a n c e , FXF = Pyp + WX, .

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Aerodynamic separation of gases and isotopes : recent advances by E Phillip Muntz; John F Wendt


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