By C. A. McAuliffe
ISBN-10: 1349815586
ISBN-13: 9781349815586
ISBN-10: 1349815608
ISBN-13: 9781349815609
The authors of this quantity have reviewed transition steel complexes containing monodentate phosphines, monodentate arsines and stiines, bidentate arsines, and multidentate team VB ligands. a piece at the nature of the bond shaped among transition metals and workforce VB ligands has additionally been incorporated, on account that this subject has been the topic of a lot dialogue lately, and a reassessment of the character of this interplay turns out well timed. typically complexes containing organometallic ligands were excluded, even supposing carbonyls were incorporated. we've got hence taken care of the final zone of coordination chemistry and never of organometallic chemistry
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Extra info for Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands
Sample text
Bellon, P. , Chern. Cornrnun. (1966),507. 109. , Ricci, G. M. , and Bellon, P. ,Inorg. , 8 (1969), 2109. 110. Albano, V. , Bellon, P. , Chern. Cornrnun. (1969),899. 111. , J. chern. Soc. (A) (1970),1313. 112. Francis, J. , and Ibers, J. ,J. organornetal. , 29 (1971),131. 113. , Francis, J. , and Ibers, J. ,J. organornetal. , 29 (1971),149. 114. Nyburg, S. , personal communication reported in ref. [112]. 115. Glanville, J. , Stewart, 1. , and Grim, S. ,1. organornetal. , 7 (1967),9. 116. Cook, C.
Soe. (Dalton) (1972),248. 84. Hillier, I. , Marriott, J. , Saunders, V. , Ware, M. , Lloyd, D. , ehern. Cornrnun. (1970),1586. References 31 85. Hillier,1. , Saunders, v. , Ware, M. , Bassett, P. , Lloyd, D. , Chern. Cornrnun. (1970), 1316. 86. Green, J. , King, D. , and Eland, J. D. , Chern. Cornrnun. (1970),1121. 87. Hillier,1. , and Saunders, V. , Chern. Cornrnun. (1970),316. 88. Hillier, 1. , and Saunders, V. ,J. chern. Soc. (A) (1971),664. 89. , Chern. Cornrnun. (1971),996. 90. Guest, M. , Hillier, 1.
14 Group VB to Transition Metal Bonds for the metallated phosphite ligands. The metal-chlorine distances in the rhodium(II1) and iridium(III) complexes indicate that the trans influences of the phosphine and phosphite ligands are very similar. 35. The affinity of triethyl phosphite for the site trans to hydride in the ruthenium(II) complex [RuHCl(CO)(PhR2PhL] was found on the basis of measured displacement equilibria to be about the same as dimethylphenylphosphine and somewhat greater than triethylphosphine 52 • These observations do not enable us to make a rigorous comparison between phosphites and phosphines, and ifwe take them as being a reliable indication of the behaviour of these ligands in positive oxidation states, they are rather difficult to explain on any reasonable basis.
Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands by C. A. McAuliffe
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