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ISBN-10: 0470772263

ISBN-13: 9780470772263

ISBN-10: 0471915564

ISBN-13: 9780471915560

Content:
Chapter 1 the appliance of sonochemistry within the formation and reactions of metal—carbon bonds (pages 2–30): D. Bremner
Chapter 2 The photochemistry of organometallic compounds (pages 31–62): Conor Long
Chapter three Phase?transfer catalysis in organometallic chemistry (pages 63–106): Jean?Francois Petrignani
Chapter four Enantioselective syntheses with optically energetic transition steel catalysts (pages 109–146): H. Brunner
Chapter five Organometallic oxidation catalysts (pages 147–198): Gabor Speier
Chapter 6 Olefin metathesis (pages 199–228): W. James ceremonial dinner and Vernon C. Gibson
Chapter 7 using transition steel clusters in natural synthesis (pages 231–317): G. Suss?Fink and F. Neumann
Chapter eight Lanthanide reagents in natural synthesis (pages 319–396): Gary A. Molander
Chapter nine using organoantimony and organobismuth compounds in natural synthesis (pages 397–433): Leon D. Freedman and George O. Doak
Chapter 10 organic and environmental methylation of metals (pages 438–463): Peter J. Craig
Chapter eleven Bioorganotin compounds (pages 465–533): Kieran C. Molloy

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Extra resources for The Metal - Carbon Bond: Volume 5 (1989)

Sample text

02) and this presumably results from the efficient internal conversion from the L F to the inactive MLCT state. In the presence of an entering ligand (L), the cis-substituted product is formed following photolysis (reaction 4)36. OMe I (CO),W=C I Ph OMe I hv -(CO),W=C L t L \ + co (4) Ph The vacant coordination site cis to the carbene moiety provides an ideal environment for thermal chemistry of the carbene with added ligands. One such example is given in Scheme 237,in which metathesis of the olefinic species is observed.

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Schubert, and H. H. Wang, J. Phys. , 87, 2299 (1983). 16. S. V. Ley, C. M. R. Low, and A. D. White, J. Organomet. , 302, C13 (1986). 17. D. Rehorek and E. G. Janzen, J. , 268, 135 (1984). 18. K. Imi, K. Imai, and K. , 28, 3127 (1987). 19. P. Renaud, Bull. Chim. , Ser. 5 , 17, 1044 (1950). 20. W. Slough and A. R. Ubbelohde, J. Chem. , 918 (1957). 21. See refs 26 and 35. 22. M. W. T. Pratt and R. Helsby, Nature (London), 184, 1694 (1959). 23. T. Azuma, S. Yanagida, H. Sukarai, S. Sasa, and K. Yoshino, Synth.

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