By S. Angus, B. Armstrong, K. M. de Reuck
ISBN-10: 0080223737
ISBN-13: 9780080223735
Foreign Thermodynamic Tables of the Fluid kingdom - 7 Propylene (Propene) is a compilation of
internationally agreed values of the equilibrium thermodynamic houses of propylene.
This booklet consists of 3 chapters, and starts with the presentation of experimental results of thermodynamic stories in comparison with the equations used to generate the tables. The succeeding bankruptcy offers with correlating equations for thermodynamic estate selection of propylene. The final bankruptcy offers the tabulations of the propylene's thermodynamic houses and constants.
This publication will turn out necessary to actual chemists.
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Additional resources for International Thermodynamic Tables of the Fluid State. Propylene (Propene)
Sample text
50. The initial assembly of terms, from which the most significant were found, were members of the equation Ρ - ρΚΓ = Σ Σ ηαΡιΤ where Ε = exp + Ε Σ Σ nbPkTl (γρ2) and the relation of na to i and /, and of nb to k and 1 is shown below, the assembly being substantially the same as that used by Jacobsen ( 4 8) in constructing an equation for nitrogen by a forward selection least-squares technique. / 2 3 4 5 6 7 8 9 11 3 "l 2 n2 1 "3 "8 3 5 7 9 11 13 15 nA "l8 "|9 -2 -3 -4 "33 "34 "35 "38 "39 "37 "36 "40 "41 "42 "43 "44 "45 "46 "47 "48 "49 "50 -3 - 1 -2 "5 "6 "7 n9 "lO "11 "12 "15 "16 "17 0 "l3 / k 1 2 "20 "21 "22 "23 "24 «25 "26 "27 "28 Π 29 "30 "31 "32 32 CORRELATING EQUATIONS The equation of state resulting from this search procedure is + n9 + n 1 0 T _ 1 ) Ρ - pRT = p2(n5 + neT~l + n7T~2) + p\n%T + ρ ( η 1 5Γ - + η 1 6Γ - ) 4 1 2 + η 1 9Γ + n 2 0 + η 2 2Γ ~ 2 ) + ρ\ηλ%Τ2 + Ρ 6(/ϊ 24Γ- 2) + ρ 7 ( η 2 6Γ - 2 ) + Ρ 8 ( " 2 8Γ - 2 ) + ρ 3 £ ( η 3 5Γ - 4 ) + ρ5Ε(η3ΊΤ-Α) + p9E{nmT~2) where + ρ'Ε^Τ1) + ρ η Ε ( η 4 3 Γ - 2 ) + ρ 7 £ ( η 3 8Τ - 2 ) Ε = exp ( - p 2 / p c 2 ) .
6 K. The apparatus and differential piezometer technique were described in ref. 34a. The results were not used in constructing the equation of state but values predicted from it are in good agreement, as shown in Figure 8. The mean deviation of the calculated values from the experimental is ± 5 . 4 K. 300 400 500 Temperature / Κ Figure 8. 3 Isobaric Heat Capacity The distribution of the experimental values of the isobaric heat capacity is shown on Fig. 15. In 1974 Bier, Ernst, Kunze and Maurer, ( 3 6) of the Universität Karlsruhe (TH), published 152 experimental results in the gas phase from 298 Κ to 473 K.
The expressions used for calculating the heat capacities are, T\dpldT)W and _ T(dpldT)2B The adiabatic indices were calculated from = Ύ CP Cv w1 (dPldph = and In the liquid phase the experimental isobaric heat capacities and densities were graphically smoothed and enthalpies and entropies derived from graphical integration of the heat capacities. Auxiliary equations are given for the second virial coefficient and ideal gas heat capacity as a function of temperature, but equations are not presented for the vapour pressure or orthobaric density curves.
International Thermodynamic Tables of the Fluid State. Propylene (Propene) by S. Angus, B. Armstrong, K. M. de Reuck
by Kenneth
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