New PDF release: Chlorine. International Thermodynamic Tables of the Fluid

By S. Angus

ISBN-10: 0080307132

ISBN-13: 9780080307138

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Example text

2 Sec. 3 Sec. 3 Sec. 3 Sec. 2 Construction of the Tables The tentative tables were produced from the equation of state whose development was described in section 3. 1. 49 50 TENTATIVE TABLES In computing the tables it was more useful to write the equation as 18 (21) P=pRT(1+ ~= The N' are listed in Table H, and the (C )' are given in Table I. For the calculation of other properties, the partial derivatives of the pressure were required. Writing them as 18 ~aP~ap> T = R T (1 + N,(Cr),) (22) N~ (CT)~~ (23) ~= and 18 (aP/ar)p = Rp(1 + i =1 they were calculated from the N~ in Table H and the (C r)' and (XT)' in Table I.

O 200 700 600 500 Temperature /E O Estimated data - PVT data 300 400 800 900 Figure 10 . Distribution of estimated speed of sound data. I000 24 ESTIMATION OF PROPERTIES equation of state, and as there is no other data available in this region it was considered that values in this region would ensure the correct qualitative behaviour of the equation. Estimated values in the near critical region were omitted however since extremely large deviations between accurate values and estimated values were found for all the fluids tested.

40 CORRELATING EQUATIONS 500 500 o 00 0 00 00 00 0 00 0 000 00 00000'•0 0 —o 0 O 0 -500 i T i 200 Estimated data I 1 1 1 250 300 350 400 Temperature / K Figure 18. Comparison of estimated enthalpy of evaporation data with values calculated from the equation of state. Eucken and Karwat to • D — • • Giauque and Powell - Equation of state D • 65 i i 200 250 Temperature / K Figure 19. Variation of isobaric heat capacity in the liquid phase at saturation, showing the available experimental results .

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Chlorine. International Thermodynamic Tables of the Fluid State by S. Angus

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