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ISBN-10: 0875900038

ISBN-13: 9780875900032

ISBN-10: 1118668960

ISBN-13: 9781118668962

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Published by way of the yank Geophysical Union as a part of the Geophysical Monograph Series.

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Read or Download Atmospheric Chemistry of Chlorine and Sulfur Compounds: Proceedings of a Symposium Held at the Robert A. Taft Sanitary Engineering Center, Cincinnati, Ohio, November 4-6, 1957 PDF

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Additional info for Atmospheric Chemistry of Chlorine and Sulfur Compounds: Proceedings of a Symposium Held at the Robert A. Taft Sanitary Engineering Center, Cincinnati, Ohio, November 4-6, 1957

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You get any seriouserror introducedin this proDr. Eriksson--No. We have checkedthe laboratoryair, of termine iodine and boron. course,to be sure on this point. Dr. Johnstone--Do you filter the air that is Dr. Morris Katz--Dr. Eriksson,doesthe sysused in the laboratory? tem of analysisthat,you have just discussed reDr. Eriksson--Yes, through cotton wool. You late to the water solublefraction of your matesee,the place where theseanalysesare done has rial ? Dr. Eriksson--Yes. very pure air. Dr. Joh•stone--This is astonishing; !

4 gram methyl red in chloride solution. one liter of methyl alcohol. Hydrogen peroxide method--This method Procedure--Add three drops of mixed indiconsistsof trapping the sulfur dioxidein an cator solution to 75 ml of absorbingsolutionin impingeror a bubblercontaining hydrogen per- a Greenburg-Smithimpinger. Neutralize the oxide. The sulfuric acid formed may be titrated with standard alkali and the sulfur dioxide may then be estimated in this manner. 002 N sodiumhydroxidesolution; not more than a few dropsshouldbe necessary not interfere in the titration.

Hydrogen sulfideand other volatile sulfides do not interfere in the hydrogen peroxidemethod. Hydrogen peroxide generally contains free sulfuric acid. In order to free the peroxidefrom suIfate, start with 30% hydrogen peroxide,dilute somewhat,neutralizewith barium hydroxide solutionusing bromophenolblue solutionas the indicator. After the reagent has serried in the cold, filter from the barium sulfate and determine the exact strength of the hydrogenperoxide by permanganatetitration. Finally, adjust to a 3% strength.

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Atmospheric Chemistry of Chlorine and Sulfur Compounds: Proceedings of a Symposium Held at the Robert A. Taft Sanitary Engineering Center, Cincinnati, Ohio, November 4-6, 1957


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