By Mitsugi Senda
ISBN-10: 0408704632
ISBN-13: 9780408704632
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Extra resources for Analytical Chemistry–4. International Union of Pure and Applied Chemistry
Example text
Majer, R. Perry and W. I. Stephen, Anal. Chim. Acta, 43, 451 (1968). M. G. Allcock, R. Belcher, J. R. Majer and R. Perry, Anal. , 42, 776 (1970). J. R. Majer and M. J. A. Reade, Chem. , 58 (1970). 27 SUR L'ANALYSE DES REACTIONS EN MILIEU NON-AQUEUX AU MOYEN DES METHODES ELECTROCHIMIQUES G. L, 10 rue Vauquelin, Paris, 5 e , France RESUME Les méthodes électrochimiques sont appliquées à l'analyse des propriétés chimiques et électrochimiques dans les divers melanges eau-acide sulfurique. On montre que les mélanges les plus concentrés en acide se comportent comme des solvants anhydres d'un grand intérêt industriel.
En outre, le potentiel normal du système est indiqué sur la courbe. La Figure 2 permet de comprendre comment les auteurs ont opéré. En ordonnées figurent les potentiels d'oxydo-réduction par rapport à l'électrode normale à hydrogène dans l'eau. Nous supposons, suivant l'hypothèse de Strehlow que le système du ferrocene a un potentiel normal indépendant du solvant qui est de 0,40 V dans l'eau, courbe 1. ^SO^aq Lu I -Réduction de solvant sur le platine poli ob 1M 0 „^'Réduction de solvant sur le platine platine 9M 15M 12M 0,25 0,50 Fraction molaire de H2SO^ 18M 0,75 Figure 2.
Acta, 45, 305 (1969). R. Belcher, J. R. Majer, W. I. Stephen, I. J. Thomson and P. C. Uden, Anal. Chim. Acta, 50, 423 (1970). R. Belcher, J. Majer, R. Perry and W. I. Stephen, J. Inorg. Nucl. , 31, 471 (1969). W. I. Stephen, I. J. Thomson and P. C. Uden, Chem. , 269 (1969). R. Belcher, W. I. Stephen, I. J. Thomson and P. C. Uden, J. Inorg. Nucl. , 33, 1851 (1971). R. Belcher, W. I. Stephen, I. J. Thomson and P. C. Uden, Chem. , 1019 (1970). R. J. D. Thesis, University of Birmingham (1971). M. Miyazaki, T.
Analytical Chemistry–4. International Union of Pure and Applied Chemistry by Mitsugi Senda
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